Search results for "WAXS and SAXS study"

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The effect of macromolecular architecture of ethylene copolymers with multi-alkenylsilsesquioxane on morphological, rheological and dynamic mechanica…

2021

Abstract The influence of the degree and the way of incorporation of multi-alkenylsilsesquioxane into the polymer chain on morphological, rheological and dynamic mechanical parameters were determined. It was found that POSS incorporated into the polymer chain was located outside the crystalline structure of lamella in amorphous phase. The incorporation of POSS-6-2 as a pendant group resulted in significant increase of separation of macromolecules. The key factor in rheological and dynamic mechanical behavior of copolymers turned out to be the way of POSS incorporation into the polymer chain. The incorporation of POSS into the polymer chain as a pendant group resulted in decreased relaxation…

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsOrganic Chemistry02 engineering and technologyPolymerWAXS and SAXS study010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesCrystallinityLamella (surface anatomy)chemistryRheologyChemical engineeringViscoelastic propertiesMaterials ChemistryCopolymerMulti-alkenyl polyhedral oligomeric silsesquioxanes (POSS)0210 nano-technologyPendant groupGlass transitionMacromoleculePolymer
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